Boris Lubomirov SHIVACHEV Assоciate Professor, PhD |
Institute of Mineralogy and Crystallography
(CLMC),
Laboratory of X-ray analysis
Bulgarian Academy of Sciences (BAS)
Web site: http://www.clmc.bas.bg
1113 Sofia, Acad. G. Bonchev Str., Bl.
107, Bulgaria
Phone: (+3592) 8700161/47; Fax.:
(+3592) 9797056;
E-mail: blsclmcbasbg
CURRICULUM VITAE:
EDUCATION AND ACADEMIC DEGREES OBTAINED:
COURSES:
LIST OF SELECTED PUBLICATIONS:
[66] R.P. Nikolova, B.L. Shivachev, S. Ferdov, Crystal
structures of Mg2+, Ba2+ and Cs+ exchanged
K–Na–ETS-4, Microporous and Mesoporous Materials, 165 (2013) 121-126.
[65] B.S. Blagoev, S.D. Terzieva, T.K. Nurgaliev, B.L.
Shivachev, A.J. Zaleski, V. Mikli, A.D. Staneva, A.K. Stoyanova-Ivanova,
Magnetic and transport characteristics of oxygenated polycrystalline La0.6Pb0.4MnO3,
Journal of Magnetism and Magnetic Materials, 329 (2013) 34-38.
[64] G. Yankov, L. Dimowa, N. Petrova, M. Tarassov, K.
Dimitrov, T. Petrov, B.L. Shivachev, Synthesis, structural and non-linear
optical properties of TeO2–GeO2–Li2O glasses,
Optical Materials, 35 (2012) 248-251.
[63] S. Stoyanov, P. Petrov, M. Stoyanova, M. Dangalov, B.
Shivachev, R. Nikolova, I. Petkov, 4-Amino-3-nitro naphthalimides—Structures and
spectral properties, Journal of Photochemistry and Photobiology A: Chemistry,
250 (2012) 92-98.
[62] G.M. Dobrikov, I. Philipova, R. Nikolova, B.
Shivachev, A. Chimov, V. Dimitrov, Functionalized organolithium reagents in the
synthesis of chiral ligands for catalytic enantioselective addition of
diethylzinc to aldehydes, Polyhedron, 45 (2012) 126-143.
[61] P.T .
Todorov, N.D. Pavlov, B.L. Shivachev, R.N. Petrova, J. Martinez, E.D. Naydenova,
M. Calmes, Synthesis of new racemic and optically active N-phosphonoalkyl
bicyclic ss-amino acids via the kabachnik-fields reaction as potential
biologically active compounds, Heteroatom Chem, 23 (2012) 123-130.
[60] P.T. Todorov, R.P. Nikolova, E.D. Naydenova, B.L.
Shivachev, Synthesis and Structural Characterization of
Spiro(fluorene-9,4'-imidazolidine)-2',5'-dione and (9H-Fluorene-9-yl)urea, J
Chem Crystallogr, 42 (2012) 566-572.
[59] N.D. Todorov, M.V. Abrashev, S.C. Russev, V. Marinova,
R.P. Nikolova, B.L. Shivachev, Raman spectroscopy and lattice-dynamical
calculations of Sc3CrO6 single crystals, Phys Rev B, 85
(2012).
[58] V.B. Kurteva, L.M. Antonov, D.V. Nedeltcheva, A.
Crochet, K.M. Fromm, R.P. Nikolova, B.L. Shivachev, M.S. Nikiforova, Switching
azonaphthols containing a side chain with limited flexibility. Part 1. Synthesis
and tautomeric properties, Dyes Pigments, 92 (2012) 1266-1277.
[57] I. Philipova, G. Stavrakov, V. Dimitrov, Camphane-based phosphino-carboxamide ligands as P,O-chelates in Pd-catalyzed enantioselective allylic alkylation, Tetrahedron: Asymmetry, 23 (2012) 927-930.
[56] V. Dyulgerov, R.P. Nikolova, L.T. Dimova, B.L.
Shivachev, 3-Carboxy-phenyl-boronic acid-theophylline (1/1), Acta
crystallographica. Section E, Structure reports online, 68 (2012) o2320.
[55] P. Todorov, M. Calmes, B.L. Shivachev, R.P. Nikolova,
(R)-Methyl
{[(2-carb-oxy-bicyclo-[2.2.2]octan-1-yl)-ammonio]-methyl}-phos-phon-ate
dichloro-methane 0.25-solvate, Acta crystallographica. Section E, Structure
reports online, 67 (2011) o2152-2153.
[54] P. Todorov, M. Calmes, B.L. Shivachev, R.P. Nikolova,
(R)-Methyl {[(2-carboxybicyclo[2.2.2]octan-1-yl)ammonio]methyl}phosphonate
dichloromethane 0.25-solvate, Acta Crystallogr E, 67 (2011) O2152-U1578.
[53] A. Stoyanova-Ivanova, S. Georgieva, T. Nedeltcheva, L.
Dimova, B. Shivachev, Variation of the unit cell parameters of the
REBa(2)Cu(3)O(y) (RE = Gd, Er) ceramics in function of the oxygen content, Bulg
Chem Commun, 43 (2011) 320-324.
[52] S. Stanchev, R.P. Nikolova, B.L. Shivachev, I.
Manolov, Crystal structure of 3-oxo-2-(4-hydroxybenzylidene)-butyric acid ethyl
ester, Bulg Chem Commun, 43 (2011) 316-319.
[51] I. Philipova, G. Stavrakov, A. Chimov, R. Nikolova, B.
Shivachev, V. Dimitrov, Synthesis of ferrocene-based amido-phosphine ligands via
highly diastereoselective ortho-lithiation and their application in Pd-catalyzed
asymmetric allylic alkylations, Tetrahedron-Asymmetr, 22 (2011) 970-979.
[50] L. Ivanova, C. Popov, I. Kolev, B. Shivachev, J.
Karadjov, M. Tarassov, W. Kulisch, J.P. Reithmaier, M.D. Apostolova,
Nanocrystalline diamond containing hydrogels and coatings for acceleration of
osteogenesis, Diamond and Related Materials, 20 (2011) 165-169.
[49] P.J. Gorolomova, R.P. Nikolova, B.L. Shivachev, V.I.
Ilieva, D.T. Tsekova, T.D. Tosheva, E.S. Tashev, S.G. Varbanov, G.G. Gencheva,
Theoretical and experimental studies on the coordination ability of
1,4-bis(dimethylphosphinylmethyleneoxy)benzene, Bulg Chem Commun, 43 (2011)
244-253.
[48] M. Gerova, R. Nikolova, B. Shivachev, O. Petrov,
Synthesis and crystal structure of
2-[(2,3-dihydro-2-oxo-3-benzoxazolyl)methyl]benzoic acid, Bulg Chem Commun, 43
(2011) 230-235.
[47] L. Dimova, B.L. Shivachev, R.P. Nikolova, Single
crystal structure of pure and Zn ion exchanged clinoptilolite: Comparison of low
temperature and room temperature structures and Cu vs. Mo radiation, Bulg Chem
Commun, 43 (2011) 217-224.
46. J. I. Yeh, Boris Shivachev, Srinivas Rapireddy, Matthew J. Crawford, Roberto
R. Gil, Shoucheng Du, Marcela Madrid and Danith H. Ly. (2010) Crystal Structure
of Chiral γPNA with Complementary DNA Strand: Insights into the Stability and
Specificity of Recognition and Conformational Preorganization. J. Am. Chem.
Soc., DOI: 10.1021/ja907225d.
45. Stoyanova, M. P., Angelova, S. E., Petrov, P. Y., Nikolova, R. P., &
Shivachev, B. L. (2010). Synthesis of 1,2,3,4-substituted spiroheterocyclic
tetrahydroisoquinoline- 1-ones and their structural similarity in water solution
and in crystallohydrate solid state. Arkivoc, 2010(2), 303-314.
44. Bistra Stamboliyska, Voislava Janevska, Boris Shivachev, Rosica P. Nikolova,
Goran Stojkovic, Bozhna Mikhova and Emil Popovskib. (2010) Experimental and
theoretical investigation of the structure and nucleophilic properties of
4-aminocoumarin. Arkivoc, 2010, 62-76.
43. Apostolova, M. D., Nikolova, R. P., & Shivachev, B. L. (2010).
(4-carbamoylphen-yl) boronic acid. Acta Crystallographica E, 66(6) .
42. Todorov, P., Naydenova, E., Nikolova, R. P., & Shivachev, B. L. (2010).
Ammonium hydrogen (RS)-[(5-methyl-2-oxo-1,3-oxazolidin-3-yl)methyl]phospho-
nate. Acta Crystallographica E, 66(1) .
41. Trajkovski, B., Karadjov, J., Shivachev, B., Dimitrova, A., Stavrev, S., &
Apostolova, M. D. (2009). Novel nanostructured materials accelerating
osteogenesis. NATO Science for Peace and Security Series B: Physics and
Biophysics, 2009, VI, Part 12, 525-532. PDF
40. Pantcheva, I. N., Dorkov, P., Atanasov, V. N., Mitewa, M., Shivachev, B. L.,
Nikolova, R. P., et al. (2009). Crystal structure and properties of the
copper(II) complex of sodium monensin A. Journal of Inorganic Biochemistry,
103(10), 1419-1424. PDF
39. Shivachev, B. L., Petrov, T., Yoneda, H., Titorenkova, R., & Mihailova, B.
(2009). Synthesis and nonlinear optical properties of TeO2-Bi2O3-GeO2 glasses.
Scripta Materialia, 61(5), 493-496. PDF
38. Shivachev, B., Petrov, P., & Stoyanova, M. (2009). Synthesis and crystal
structure of 4-methyl-6H-pyrido[3,2,1-jk]carbazol-6- one. Journal of Chemical
Crystallography, 39(3), 209-212.
37. Todorov, P. T., Petrova, R. N., Naydenova, E. D., & Shivachev, B. L. (2009).
Structure, conformation and hydrogen bonding of two
amino-cycloalkanespiro-5-hydantoins. Central European Journal of Chemistry,
7(1), 14-19. PDF
36. Terzieva, S. D., Stoyanova-Ivanova, A. K., Shivachev, B. L., Terzijska, B.
M., Zaleski, A. J., Misiorek, H., et al. (2009). Microstructure and thermal
properties of quasi-equal rare earth substitution Y0.5Gd0.5Ba2Cu3 O6.94
superconductor. Central European Journal of Physics, 7(1), 84-88.
35. Petar Y. Petrov, Nikolay G. Vassilev, Silvia E. Angelova, Boris L. Shivachev
and Galin P. Petrov. (2009) Mechanism and Stereoselectivity of the
Phosphinylation of 3-Acyl Coumarins - Stereocontrol Via Concurrent Aromatic
Interaction/Oxaphosphole Formation. Letters in Organic Chemistry, 6/2, 180-185.
PDF
34. Atanassova, M., Lachkova, V., Vassilev, N., Shivachev, B., Varbanov, S., &
Dukov, I. (2008). Effect of p-tert-butylcalix[4]arene fitted with phosphinoyl
pendant arms as synergistic agent in the solvent extraction of trivalent
lanthanoids with 4,4,4-trifluoro-1-(2-thienyl)-1,3-butanedione and structural
study of solid complexes by IR, NMR and X-ray. Polyhedron, 27(15), 3306-3312.
33. Nikolova, R. P., Kolev, T., Statkova-Abeghe, S. M., & Shivachev, B. L.
(2008). (±)-Ethyl 6,7-dimethoxy-1-(1H-pyrrol-2-yl)-1,2,3,4-tetra-
hydroisoquinoline-2-carboxylate. Acta Crystallographica E, 64(9) .
32. Kolev, Ts., Koleva, B.B., Schivachev, B. (2008). Oriented solids as a
colloid suspension in nematic liquid crystal - New tool for IR-spectroscopic and
structural elucidation of inorganic compounds and glasses. Inorganica Chimica
Acta, 361 (7), 2002-2012. PDF
31. Georgieva, G., Gencheva, G., Shivachev, B. L., & Nikolova, R. P. (2008). A
new monoclinic polymorph of dichlorido-tetra-kis(dimethyl
sulfoxide)-ruthenium(II). Acta Crystallographica E, 64(8) .
30. Stoyanova-Ivanova, A. K., Terzieva, S. D., Shivachev, B. L., Mikli, V., &
Vladimirova, L. K. (2008). Synthesis and superconducting properties of Nd0.33
Eu0.08Gd0.58Ba2Cu3 oz materials. Central European Journal of Physics, 6(1),
76-79.
29. Petrov, P. Y., Stoyanova, M., & Shivachev, B. (2008).
4-methyl-1-phenylquinolin-2(1H)-one. Acta Crystallographica E, 64(1) .
28. Kandinska, M. I., Todorov, I. S., Shivachev, B., & Bogdanov, M. G. (2007).
Trans-rac-2-hexyl-1-oxo-3-(2-pyridyl)-1,2,3,4-tetrahydroisoquinoline-4-
carboxylic acid. Acta Crystallographica E, 63(5), o2544-o2546. PDF
27. Kolev, T., Shivachev, B., & Petrova, R. (2007). 4-phenylpyridinium
3-carboxy-2,3-dihydroxypropanoate dihydrate. Acta Crystallographica E, 63(5) .
26. Zidarov, N., Shivachev, B., Kalvachev, Y., & Stanchev, H. (2007). Caledonite
from madan ore district, central rhodopes, south bulgaria. Comptes Rendus De
L'Academie Bulgare Des Sciences, 60(12), 1303-1308.
25. Petrova, R., Titorenkova, R., & Shivachev, B. (2007). Isoquinolin-1(2H)-one.
Acta Crystallographica E, 63(12) .
PDF
24. Bakalova, A., Petrova, R., Shivachev, B., & Varbanov, H. (2007). Synthesis
and crystal structure of a pt(II) complex with
3-amino-5-methyl-5-phenylhydantoin. Journal of Coordination Chemistry, 60(15),
1701-1707.
PDF
23. Kolev, T., Shivachev, B., Petrova, R., Ivanov, I., Atanasova, S., &
Statkova, S. (2007). 1,2,3,4-tetra-hydro-isoquinolinium hydrogensquarate. Acta
Crystallographica E, 63(8), o3353-o3354.
PDF
22. Kolev, T., Yancheva, D., Shivachev, B., & Petrova, R. (2007). The
pyridinium-betaine of squaric acid. Acta Crystallographica E, 63(7).
PDF
21. Todorov, P., Naydenova, E., Petrova, R., Shivachev, B., &
Troev, K. (2006). [(4,4-dimethyl-2-oxo-1,3-oxazolidin-3-yl)methyl]phosphonic
acid. Acta Crystallographica Section C: Crystal Structure Communications,
62(11), o661-o662.
20. Shivachev, B., Petrova, R., & Naydenova, E.
(2006). 3prime;-aminocyclohexanespiro-5′-hydantoin-phenylboronic acid (1/1).
Acta Crystallographica E, 62(9), o3887-o3889.
19. Petrova, N.,
Shivachev, B., Kolev, T., & Petrova, R. (2006). Sodium hydrogensquarate
monohydrate. Acta Crystallographica E, 62(6), m1359-m1361.
18.
Shivachev, B., Petrova, R., Marinova, P., Stoyanov, N., Ahmedova, A., & Mitewa,
M. (2006). Four cycloalkanespiro-4′-imidazolidine-2′,5′-dithiones. Acta
Crystallographica Section C: Crystal Structure Communications, 62(4), o211-o215.
17. Kolev, T., Bakalska, R., Shivachev, B., & Petrova, R. (2006).
Codeinone. Acta Crystallographica E, 62(1), o255-o257.
16. Kolev, T.,
Bakalska, R., Shivachev, B., & Petrova, R. (2005). 6-O-acetylcodeine. Acta
Crystallographica E, 61(8), o2582-o2584.
15. Shivachev, B., Petrova, R.,
& Naydenova, E. (2005). Dimorphism in 3′-aminocyclohexane-spiro-5′-hydantoin.
Acta Crystallographica Section C: Crystal Structure Communications, 61(8),
o524-o526.
14. Petrova, R., Shivachev, B., Kosev, K., Stoyanova, M., &
Angelova, S. (2005).
(3RS/4RS)-3-(2-furyl)-2-phenethyl-4-(pyrrolidin-1-yl-carbonyl)-3,
4-dihydroisoquinolin-1 (2H)-one. Acta Crystallographica E, 61(7), o2248-o2250.
13. Kashchieva, E., Shivachev, B., & Dimitriev, Y. (2005). Molecular
dynamics studies of vitreous boron oxide. Journal of Non-Crystalline Solids,
351(12-13), 1158-1161.
12. Shivachev, B., Kashchieva, E., & Dimitriev,
Y. (2005). DFT calculations of cluster formation in vitreous B2O 3. Physics and
Chemistry of Glasses, 46(2), 253-255.
11. Kolev, T., Yancheva, D.,
Shivachev, B., Petrova, R., & Spiteller, M. (2005).
2-(3-benzoyl-1-pyridinio)-3,4-dioxo-cyclobutenolate. Acta Crystallographica
Section C: Crystal Structure Communications, 61(4), o213-o215.
10.
Kolev, T., Yancheva, D., Shivachev, B., Petrova, R., & Spiteller, M. (2005).
2-{3-[(E)-(3,4-dimethoxyphenyl)ethenyl]-5,5-dimethylcyclohex-2-enylidene}
malononitrile. Acta Crystallographica E, 61(3), o550-o552.
9. Shivachev,
B., Petrova, R., Kossev, K., & Troev, K. (2005).
[1-(hydroxyethylammonio)propyl]phosphonate. Acta Crystallographica E, 61(1),
o134-o136.
8. Shivachev, B. L., Mincov, I. P., Kashchieva, E. P.,
Dimitriev, Y. B., Smith, R., & Troev, T. (2004). Positron lifetime spectroscopy
of vitreous B2O3. Journal of Non-Crystalline Solids, 345-346, 108-111.
7. T. Troev, B. Shivachev and T. Yoshiie. Positron Lifetime Calculations of
Defects in Nickel Containing Hydrogen at Various Temperatures, Materials Science
Forum, 445/446 (2004) 198 .
6. Shivachev, B. L., Troev, T., & Yoshiie,
T. (2002). Positron lifetime computations of defects in nickel containing
hydrogen or helium. Journal of Nuclear Materials, 306(2-3), 105-111.
5.
I. Minkov, V. Ganev, T. Troev, B. Shivachev, Temperature dependence of
crystallization in Fe78Si9B13 and Co75Si15B10 amorphous alloys using
positron-anihilation lifetime spectroscopy and powder X-ray diffraction, Meeting
in Physics Uni. Sofia, ed. A. Proykova, vol.4 Heron Press, Sofia, (2003) 133.
4. B.Shivachev, E.Kashchieva, Y. Dimitriev, I. P. Minkov. Positron
lifetime investigation of vitreous B2O3,Glass Sci.Technol.75 C2 (2002) 389.
3. B.Shivachev , E.Kashchieva , Y.Dimitriev, Computer simulations of RDF
curves for nanoclusters in vitreous B2O3, Nanoscience & Nanotechnology'02, Eds.
E.Balabanova, I.Dragieva, Heron press, Sofia (2002) 75.
2. B. Shivachev,
E. Kashchieva. Simulation de la structure des verres a base de B2O3, J. UCTM. ,
37/5 (2002) 235.
1. E.Kashchieva, B.Shivachev. Computer modelling of
vitreous B2O3 structure, Glass Sci.Technol.71C (1998) 389.
Conferences:
01. Р. П. Николова и Б. Шивачев, 2005. Кристална структура на 3Pb
(COOH)2.13tu.H2O. Юбилеен сборник 10 години ЦЛМК „ Акад. Иван Костов” 189.